盐碱滩上建起绿色甲醇工厂 天津芦竹基项目加速推进A green methanol plant has been built on the saline-alkali beach, and the Tianjin Luzhuji project is accelerating.

位于天津滨海新区大港石化产业园的10万吨/年芦竹基绿色甲醇项目正加快建设。作为天津瑞恒茂集团新能源新材料产业基地一期闭环工程的最后一环,该项目已进入收尾阶段,二期蓝图同步铺展。基地建成后预计年产值50亿元,年减排二氧化碳240万吨。
原料来自滨海盐碱滩涂上的一株草。在渤海之滨,北大港湿地接纳净化后的市政污水,成为生态补水的重要来源;滩涂上曾难以处置的市政污泥、畜禽粪便经无害化处理后化作沃土回归大地;河道两岸,芦竹扎根生长、绵延成片。一条“水、肥、土、竹、纤、醇、碳”全链条闭环,在这片土地上被重新串联起来。
把野草变成“标准件”,靠的是品种选育。在天津津南区小站镇芦竹种业创新基地,大棚里幼苗长势整齐。瑞恒茂选育的多倍体芦竹“绿州一号”可在含盐量6‰的盐碱地中生长,耐受零下20摄氏度低温,一次种植可连续收割20年;丰产期每亩年产干基4吨以上,热值达3900至4400大卡/千克,纤维素、半纤维素、木质素含量合计超过86%。瑞恒茂集团芦竹种植首席工程师王金山表示,天津滩涂、湿地、盐碱地分布广泛,芦竹的耐污性、耐盐碱性、耐金属胁迫性以及根部固氮作用,适宜用作改良土壤种植,契合本地生态环境和产业结构。
种苗繁育体系同步搭建。团队推进植物多倍体诱变、基因测序等技术攻关,选育适配能源、材料、饲料等方向的新品种;在繁育端依托一次性组培快繁、开放式组培快繁及母本脱毒复壮增殖等技术,建起标准化种苗繁育体系。按规划,到2026年芦竹种苗年产能将达2亿株,可满足20万亩种植需求。芦竹每亩可固碳5至8吨,基地一期将改良8万亩盐碱地种植芦竹,二期再新增12万亩,边际土地由此转化为可持续产出的原料基地。
绿色甲醇制造的难点,不在于“甲醇”,而在于“绿色”。该项目提出“三零工程”目标,即零化石能源使用、零新鲜水消耗、零有机固废、液废和有害气体排放。工艺上采用加压有氧生物质气化合成绿色甲醇路线,芦竹经加压有氧气化产生混合气,约30%送入燃气轮机做功,高温烟气再进余热废热锅炉产生高压蒸汽,回供气化环节使用;其余约70%的合成气用于合成甲醇,实现能量梯级利用,整套系统碳转化率达98%以上。瑞恒茂集团董事长林洪新介绍了上述工艺安排。
水与固废同样纳入闭环。瑞恒茂2012年首创智慧水务方案,把污水处理从“处理—外排”的两步路径,拓展为“处理—再生—回用—处理—趋零—低排”的六到八次循环。2025年,集团对旗下市政污水处理厂、工业污水处理厂及再生水厂实施光伏改造,吨处理能耗同比下降10%,创下建厂以来最优水平,三个水厂为甲醇项目提供稳定用水与污水处置。企业自主研发的市政污泥五段双系统负碳处理处置技术,把污泥转化为盐碱地改良剂和芦竹专用肥,每年可消纳天津污水处理厂产生的50万吨污泥;甲醇生产中的废渣又回用于肥料生产。据测算,项目每年可直接减排二氧化碳30余万吨,并获2025年氢基产业碳中和奖、全国最具投资价值华耀奖。
产品端面向多个减碳场景。绿色甲醇可直接用于车用、船用燃料,也可转化生产化工新材料;绿色纤维、可持续航空燃料分别面向纺织与民航领域的减碳需求。相关项目案例纳入京津冀重大环保专项,产业与技术路径获生态环境部认可并列入其重大专项指导目录。按规划,两期项目全部建成后基地总投资将达58亿元,预计年产值50亿元、税收3.9亿元,带动就业2000余人,年减排二氧化碳240万吨。瑞恒茂计划到2035年,在天津、河北、河南、山东、安徽、江苏、湖北、上海8省市推广复制。
The 100,000-ton-per-year green methanol project based on reed bamboo, located in the Dagang Petrochemical Industrial Park of Tianjin Binhai New Area, is accelerating construction. As the final part of the first-phase closed-loop project of the Tianjin Ruihengmao Group New Energy and New Materials Industrial Base, the project has entered the final stage, with plans for the second phase being laid out simultaneously. After completion, the base is expected to have an annual output value of 5 billion yuan and reduce carbon dioxide emissions by 2.4 million tons per year.
The raw material comes from a plant growing on the saline-alkali tidal flats in Binhai. At the edge of the Bohai Sea, the Beidagang Wetland receives purified municipal sewage, becoming an important source of ecological water replenishment; municipal sludge and livestock manure that were once difficult to dispose of on the tidal flats are treated harmlessly and return to the land as fertile soil; along both sides of the river, reed bamboo takes root and grows, stretching out in large patches. A full-chain closed loop of 'water, fertilizer, soil, bamboo, fiber, alcohol, carbon' is reconnected on this land.
Turning wild grass into a 'standard component' relies on variety breeding. At the Luzhu Seed Industry Innovation Base in Xiaozhan Town, Jinnan District, Tianjin, seedlings in the greenhouses grow uniformly. Ruihengmao's bred polyploid luzhu variety 'Lvzhou No. 1' can grow on saline-alkali soil with a salt content of 6‰, withstand temperatures as low as minus 20 degrees Celsius, and can be continuously harvested for 20 years from a single planting; during its high-yield period, it produces over 4 tons of dry matter per acre annually, with a calorific value of 3900 to 4400 kcal/kg, and a total cellulose, hemicellulose, and lignin content exceeding 86%. Wang Jinshan, chief engineer of Luzhu planting at Ruihengmao Group, stated that since tidal flats, wetlands, and saline-alkali lands are widely distributed in Tianjin, luzhu’s pollution resistance, salt-alkali tolerance, metal stress resistance, and nitrogen-fixing effect of its roots make it suitable for soil improvement planting, aligning with the local ecological environment and industrial structure.
A seedling breeding system is being built concurrently. The team is advancing technical research on plant polyploid mutation, gene sequencing, and other areas, selecting and cultivating new varieties suited for energy, materials, feed, and other purposes. On the breeding side, relying on technologies such as one-time tissue culture rapid propagation, open-type tissue culture rapid propagation, and mother plant virus-free rejuvenation and multiplication, a standardized seedling breeding system has been established. According to the plan, by 2026, the annual production capacity of Arundinaria seedlings will reach 200 million plants, meeting the planting demand for 200,000 mu. Each mu of Arundinaria can sequester 5 to 8 tons of carbon. In the first phase, 80,000 mu of saline-alkali land will be improved to plant Arundinaria, and in the second phase, an additional 120,000 mu will be added, turning marginal land into a raw material base with sustainable output.
The difficulty in producing green methanol lies not in 'methanol' itself, but in 'green'. The project proposes the 'Three Zeros Project' goals, namely zero use of fossil energy, zero consumption of fresh water, and zero emissions of organic solid waste, liquid waste, and harmful gases. The process adopts a pressurized oxygen biomass gasification route for synthesizing green methanol. Bamboo is gasified under pressurized oxygen to produce syngas, about 30% of which is sent to a gas turbine to generate power. The high-temperature flue gas then enters a waste heat boiler to produce high-pressure steam, which is returned to the gasification section for use. The remaining approximately 70% of the syngas is used to synthesize methanol, achieving cascade utilization of energy, and the overall system carbon conversion rate reaches over 98%. Lin Hongxin, Chairman of Ruihengmao Group, introduced the above process arrangement.
Water and solid waste are equally integrated into a closed loop. In 2012, Ruihengmao pioneered the smart water management solution, expanding sewage treatment from a two-step process of 'treatment—discharge' to a six- to eight-cycle process of 'treatment—regeneration—reuse—treatment—toward zero—low discharge.' By 2025, the group will implement photovoltaic upgrades at its municipal sewage treatment plants, industrial sewage treatment plants, and reclaimed water plants, reducing energy consumption per ton of treated water by 10% year-on-year, achieving the best level since the plants were built. The three water plants provide stable water supply and sewage disposal for the methanol project. The company independently developed a five-stage dual-system negative-carbon treatment and disposal technology for municipal sludge, converting sludge into saline-alkali soil conditioners and specialized fertilizer for reed bamboo, capable of processing 500,000 tons of sludge generated annually by Tianjin sewage treatment plants. The waste residue from methanol production is reused for fertilizer production. It is estimated that the project can directly reduce more than 300,000 tons of carbon dioxide annually and has received the 2025 Hydrogen-Based Industry Carbon Neutrality Award and the National Most Investment-Worthy Huayao Award.
The products target multiple carbon reduction scenarios. Green methanol can be directly used as fuel for vehicles and ships, or transformed to produce new chemical materials; green fibers and sustainable aviation fuel address the carbon reduction needs of the textile and civil aviation sectors, respectively. Relevant project cases have been included in major environmental protection initiatives in the Beijing-Tianjin-Hebei region, and the industry and technology pathways have been recognized by the Ministry of Ecology and Environment and listed in its major project guidance catalog. According to the plan, after both phases of the project are completed, the total investment in the base will reach 5.8 billion yuan, with an expected annual output value of 5 billion yuan, tax revenue of 390 million yuan, employment for more than 2,000 people, and an annual reduction of 2.4 million tons of carbon dioxide emissions. Ruihengmao plans to expand and replicate the project in eight provinces and cities by 2035: Tianjin, Hebei, Henan, Shandong, Anhui, Jiangsu, Hubei, and Shanghai.
[Source: Science and Technology Daily]
[Editor: Xiao Neng]
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